I'm not an expert on mac OS but it looks like you gave the application directory to the SDE command, instead you need to give the full application command line. For example for calculator it is: /Applications/Calculator.app/Contents/MacOS/Calculator.
Also, you should not specify both -wsm and -avx. The AVX emulator is an integral part of any CPU type that supports AVX (starting from SNB).
As you can see this is an assertion inside pin.
Looking at the code, it looks like the application is trying to suspend the current thread and this is not supported by pin.